Free surface energy change for water adsorbed on hydroxyapatite.

نویسندگان

  • H M Rootare
  • R G Craig
چکیده

The free energies of immersion for three hydroxyapatite samples of different origin and method of preparation were determined from water adsorption isotherms at 20 and 25 C. The free energies varied with the temperature of the isotherm, changing linearly with the outgassing temperature in the range of 20 and 300 C. The samples outgassed at 300 C yielded free energy of immersion values of 365, 432, and 476 ergs/cm2 for the VIC-, NBS-, and TVA-HAP, respectively. Work of adhesion and work of spreading were calculated for water on these samples.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Micromechanical measurement of active sites on silicon nitride using surface free energy variation.

We have investigated chemical reactions between adsorbed water and active sites on a silicon nitride surface as a function of temperature and relative humidity using microcantilevers. Effects that might produce a change in the response of the microcantilever, such as a mass adsorption, surface tension of the adsorbed water, and changes in thermal conductivity, were systematically investigated. ...

متن کامل

Ab initio modeling of protein/biomaterial interactions: competitive adsorption between glycine and water onto hydroxyapatite surfaces.

Both glycine and water exhibit a high affinity towards the hydroxyapatite HA surfaces. What happens when they are co-adsorbed at the HA (001) surface? B3LYP periodic calculations reveal that glycine displaces the pre-adsorbed water interacting directly with the HA surface.

متن کامل

Thermodynamics of statherin adsorption onto hydroxyapatite.

Statherin is a salivary protein that inhibits the nucleation and growth of hydroxyapatite crystals in the supersaturated environment of the oral cavity. The thermodynamics of adsorption of statherin onto hydroxyapatite crystals have been characterized here by isothermal titration calorimetry and equilibrium adsorption isotherm analysis. At 25 degrees C, statherin adsorption is characterized by ...

متن کامل

Dissolution and re-crystallization processes in multiphase silicon stabilized tricalcium phosphate.

Ultrasonically accelerated dissolution of multiphase silicon stabilized tricalcium phosphate powders in water or Earle's balanced salt solution transforms the powders into needle-like calcium deficient apatite crystals with the c-axis (001) oriented along the needle. Ion exchange with the solution occurs primarily in the first hours of immersion. The transformation is driven by an interaction b...

متن کامل

Deposition of Ultrathin Nano-Hydroxyapatite Films on Laser Micro-Textured Titanium Surfaces to Prepare a Multiscale Surface Topography for Improved Surface Wettability/Energy

The primary aim of this study was to analyse the correlation between topographical features and chemical composition with the changes in wettability and the surface free energy of microstructured titanium (Ti) surfaces. Periodic microscale structures on the surface of Ti substrates were fabricated via direct laser interference patterning (DLIP). Radio-frequency magnetron sputter deposition of u...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Journal of dental research

دوره 56 7  شماره 

صفحات  -

تاریخ انتشار 1977